: The "Sun King" is infatuated with her beauty and attempts to make her his official mistress; Angélique skillfully navigates his advances while maintaining her autonomy and searching for the truth about Peyrac.

: Her second husband and cousin; their marriage is one of convenience and social status, marked by mutual disdain that eventually softens into a complex, cold respect before his death in battle.

: Angélique often uses her "busty" and "angelic" appearance to manipulate powerful men to protect herself and her children.

: Initially forced to marry the wealthy and scarred Count Joffrey de Peyrac, Angélique is at first repulsed by his appearance and rumors of sorcery.

: She eventually falls deeply in love with him, won over by his intellect, kindness, and progressive spirit.